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碳中和 4

节能减排 4

薄膜润滑 3

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Pt–Ba–Ce/γ-Al₂O₃ 催化剂，物理化学性质，NO_x存储和还原，NO_x 排放，H₂ 还原剂 1

一水硬铝石 1

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Effect of different high viscosity modifiers on rheological properties of high viscosity asphalt

《结构与土木工程前沿（英文）》 2021年第15卷第6期页码 1390-1399 doi: 10.1007/s11709-021-0775-z

摘要： High viscosity asphalt (HVA) has been a great success as a drainage pavement material. However, the larger porosity of drainage asphalt mixtures weakens the cohesion and adhesion and leads to premature rutting, water damage, spalling and cracking. The purpose of this study was to investigate the rheological properties of HVA prepared using different high viscosity modifiers through conventional tests, Brookfield viscosity tests, dynamic shear rheometer tests and bending beam rheometer tests. The conventional performance results demonstrated SBS + rubber asphalt (SRA-1/2) exhibited excellent elastic recovery and low-temperature flexibility. The 60°C dynamic viscosity results indicated TPS + rubber asphalt (TRA) had the excellent adhesion. The rotational viscosity results and rheological results indicated that SRA-2 not only exhibited excellent temperature stability and workability, as well as excellent resistance to deformation and rutting resistance, but also exhibited excellent low-temperature cracking resistance and relaxation performance. Based on rheological results, the PG classification of HVA was 16% rubber + asphalt for PG76-22, 20% rubber + asphalt for PG88-22, TRA and SRA-1/2 for PG88-28. From comprehensive evaluation of the viscosity, temperature stability and sensitivity, as well as high/low temperature performance of HVA, SRA-2 was found to be more suited to the requirements of drainage asphalt pavement materials.

关键词： high viscosity asphalt rheological properties rubber modifier viscosity

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Simultaneous saccharification and fermentation of sweet potato powder for the production of ethanol under conditions of very high gravity

Yinxiu CAO, Hongchi TIAN, Kun YAO, Yingjin YUAN

《化学科学与工程前沿（英文）》 2011年第5卷第3期页码 318-324 doi: 10.1007/s11705-010-1026-3

摘要： Due to its merits of drought tolerance and high yield, sweet potatoes are widely considered as a potential alterative feedstock for bioethanol production. Very high gravity (VHG) technology is an effective strategy for improving the efficiency of ethanol fermentation from starch materials. However, this technology has rarely been applied to sweet potatoes because of the high viscosity of their liquid mash. To overcome this problem, cellulase was added to reduce the high viscosity, and the optimal dosage and treatment time were 8 U/g (sweet potato powder) and 1 h, respectively. After pretreatment by cellulase, the viscosity of the VHG sweet potato mash (containing 284.2 g/L of carbohydrates) was reduced by 81%. After liquefaction and simultaneous saccharification and fermentation (SSF), the final ethanol concentration reached 15.5% (v/v), and the total sugar conversion and ethanol yields were 96.5% and 87.8%, respectively.

关键词： bioethanol sweet potato very high gravity viscosity reduction simultaneous saccharification and fermentation

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New approach to determine the plastic viscosity of self-compacting concrete

M. BENAICHA,X. ROGUIEZ,O. JALBAUD,Y. BURTSCHELL,A. Hafidi ALAOUI

《结构与土木工程前沿（英文）》 2016年第10卷第2期页码 198-208 doi: 10.1007/s11709-015-0327-5

摘要： The rheology of concrete is best measured with the use of a rheometer. The slump flow test gives a good indication of the flowability of the mixture and is therefore still used extensively to judge the workability of SCC mixtures. However, this test presents some defects. The objective of this paper is to develop a new methodology for measuring the workability of a SCC. In this article, we have proposed a correlation between the plastic viscosity of concrete, the time and the characteristics of the flow final profile from the V-funnel coupled to a Plexiglas horizontal channel. The proposed approach, verified by experimental results, represents a simple, economical and usable tool on building site, and it allows to characterize rheologically the SCC from its flow. The comparison between our approach and the experimental values of the plastic viscosity shows that, in a laboratory or on site, instead of using a rheometer we can use our approach to characterize the rheological behavior of a SCC.

关键词： rheology viscosity V-funnel flow profile rheometer behavior

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A critical review of ash slagging mechanisms and viscosity measurement for low-rank coal and bio-slags

Md Tanvir ALAM, Baiqian DAI, Xiaojiang WU, Andrew HOADLEY, Lian ZHANG

《能源前沿（英文）》 2021年第15卷第1期页码 46-67 doi: 10.1007/s11708-020-0807-8

摘要： Gasification or combustion of coal and biomass is the most important form of power generation today. However, the use of coal/biomass at high temperatures has an inherent problem related to the ash generated. The formation of ash leads to a problematic phenomenon called slagging. Slagging is the accumulation of molten ash on the walls of the furnace, gasifier, or boiler and is detrimental as it reduces the heat transfer rate, and the combustion/gasification rate of unburnt carbon, causes mechanical failure, high-temperature corrosion and on occasions, superheater explosions. To improve the gasifier/combustor facility, it is very important to understand the key ash properties, slag characteristics, viscosity and critical viscosity temperature. This paper reviews the content, compositions, and melting characteristics of ashes in differently ranked coal and biomass, and discusses the formation mechanism, characteristics, and structure of slag. In particular, this paper focuses on low-rank coal and biomass that have been receiving increased attention recently. Besides, it reviews the available methodologies and formulae for slag viscosity measurement/prediction and summarizes the current limitations and potential applications. Moreover, it discusses the slagging behavior of different ranks of coal and biomass by examining the applicability of the current viscosity measurement methods to these fuels, and the viscosity prediction models and factors that affect the slag viscosity. This review shows that the existing viscosity models and slagging indices can only satisfactorily predict the viscosity and slagging propensity of high-rank coals but cannot predict the slagging propensity and slag viscosity of low-rank coal, and especially biomass ashes, even if they are limited to a particular composition only. Thus, there is a critical need for the development of an index, or a model or even a measurement method, which can predict/measure the slagging propensity and slag viscosity correctly for all low-rank coal and biomass ashes.

关键词： slag viscosity biomass low-rank coal combustion gasification

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粘-温修正的等效粘度模型分析研究

曲庆文

《中国工程科学》 2005年第7卷第5期页码 49-52

摘要：

在等效粘度模型的基础上，考虑温度对润滑剂粘度的影响，建立了粘-温修正的等效粘度分析计算模型，并运用该模型进行薄膜润滑条件下的轴承性能分析计算，得到了不同参数下轴承性能的变化规律。

关键词：薄膜润滑粘度温度

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Crystallization and viscosity-temperature characteristics during co-gasification of industrial sludge

Linmin ZHANG, Bin LIU, Juntao WEI, Xudong SONG, Yonghui BAI, Jiaofei WANG, Ying ZHOU, Huijun YANG, Guangsuo YU

《能源前沿（英文）》 2022年第16卷第6期页码 1037-1047 doi: 10.1007/s11708-022-0824-x

摘要： Co-gasification of industrial sludge (IS) and coal was an effective approach to achieve harmless and sustainable utilization of IS. The long-term and stable operation of a co-gasification largely depends on fluidity of coal-ash slag. Herein, the effects of IS addition on the crystallization and viscosity of Shuangmazao (SMZ) coal were investigated by means of high temperature stage coupled with an optical microscope (HTSOM), a scanning electron microscopy coupled with an energy dispersive X-ray spectrometry (SEM-EDS), X-ray diffraction (XRD), a Fourier transform infrared spectrometer (FTIR), and FactSage software. The results showed that when the proportion of IS was less than 60%, with the addition of IS, the slag existed in an amorphous form. This was due to the high content of SiO₂ and Al₂O₃ in SMZ ash and blended ash, which had a high glass-forming ability (GFA). The slag formed at a high temperature had a higher polymerization degree and viscosity, which led to a decrease in the migration ability between ions, and ultimately made the slag difficult to crystallize during the cooling. When the proportion of IS was higher than 60%, the addition of IS increased the CaO and FeO content in the system. As network modifiers, CaO and FeO could provide O²⁻ at a high temperature, which reacted with silicate network structure and continuously destroyed the complexity of network structure, thus reducing the polymerization degree and viscosity of slag. At this time, the migration ability between ions was enhanced, and needle-shaped/rod-shaped crystals were precipitated during the cooling process. Finally, the viscosity calculated by simulation and Einstein-Roscoe empirical formula demonstrated that the addition of IS could significantly improve the fluidity of coal ash and meet the requirements of the liquid slag-tapping gasifier. The purpose of this work was to provide theoretical support for slag flow mechanisms during the gasifier slagging-tapping process and the resource treatment of industrial solid waste.

关键词： co-gasification industrial sludge crystallization viscosity mineral matter evolution

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指数型粘度修正模型及应用

曲庆文,王梅,柴山,姚福生

《中国工程科学》 2001年第3卷第10期页码 53-58

摘要：

根据吸附理论和分子间能量的变化规律来确定表面相互作用程度，以此可定义吸附层，得出吸附层厚度的分析计算式。吸附层厚度对研究薄膜润滑是最关键的因素，是薄膜与厚膜不同分析的关键点。根据分子相互作用的基本理论及流体力学的基本定义得出指数型粘度修正的表达式，用于确定微小间隙内流体粘度的变化规律，从而建立薄膜润滑理论模型，计算薄膜润滑轴承的特性。

关键词：吸附层粘度薄膜润滑轴承

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连续粘变条件下的速度场分析

曲庆文,王梅,陈海真,柴山,姚福生

《中国工程科学》 2002年第4卷第6期页码 29-32

摘要：

流体的流动状态将直接影响轴承的润滑特性，轴承的润滑特性主要由润滑剂的粘度决定。工作中润滑剂的粘度变化影响其运动速度的变化，从而影响润滑剂的温升及内剪切稀化的程度等。尤其在薄膜润滑中，润滑膜的厚度极小，润滑剂流体粒子间的相对运动速度增大，其润滑剂特性的变化更为突出。以连续变化的粘度修正模型来研究在微小间隙内润滑剂的速度特性，得出间隙内速度的分布规律，为研究薄膜流体温度场和剪切稀化问题提供计算数据。

关键词：薄膜润滑粘度连续模型速度

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新型高黏度改性沥青的研发和应用

杨林江

《中国工程科学》 2008年第10卷第12期页码 92-96

摘要：

针对杭州湾大桥桥面铺装对高黏度改性沥青的技术要求，研发了一种新型高黏度改性沥青［1］。通过分析基质沥青、SBS、化学助剂的红外光谱，在研究沥青改性过程中微观结构变化规律的基础上，提出了采用SBS加化学接枝反应剂（增黏剂）TW-1和增容剂TW-2的沥青改性配伍设计，使改性沥青在提高低温延度、弹性恢复能力的同时，大幅度提升了60 ℃动力黏度，而施工和易性不受影响，产品在杭州湾大桥工程中得到了成功的应用。

关键词：杭州湾大桥高黏度改性沥青配伍机理红外光谱分析路用性能施工性能

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Properties of cement grout modified with ultra-fine slag

Sowmini GOPINATHAN, K B ANAND

《结构与土木工程前沿（英文）》 2018年第12卷第1期页码 58-66 doi: 10.1007/s11709-017-0383-0

摘要： The purpose of the study is to obtain a cement grout with improved performance. The grout mixes of the present study contain cement, ultra-fine slag (UFS), super plasticizer and water. Properties like flowability, bleeding, compressive strength and shrinkage of cement grouts have been studied. Rheological parameters were also studied in order to explain the grout workability. The results show that, cement replacement with slag in grouts could reduce bleeding substantially without affecting the workability of the mixes. Introduction of slag enhanced the compressive strength and reduced shrinkage reasonably. Ultra-fine slag can be used as a supplementary cementitious material in cementitious grouts in order to improve the grout behavior.

关键词： cement grout ultra-fine slag flowability bleeding viscosity

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Simulation of cottonseed cake melt flow in metering zone of a single screw extruder

Hong HE, Jianguo ZHOU,

《化学科学与工程前沿（英文）》 2010年第4卷第3期页码 263-269 doi: 10.1007/s11705-009-0276-4

摘要： Research on the extrusion of natural polymers (food, feed, etc.) is relatively new due to the complex physicochemical transformations of raw materials, although plastics melt conveying and transport have been well studied. The structure and composition, rheological behavior as well as extrusion processing of natural polymer are much more complicated. In this study, a quasi-three-dimensional (3D) fluid flow model for non-Newtonian, non-isothermal and undeveloped temperature was developed, the model prediction being in reasonably good agreement with the experiment. Results show that the influence of moisture content, among other process variables, is the most significant, followed by screw speed. Some interaction exists between these two variables and the screw speed effect becomes marginal at high moisture contents. In addition, viscosity change in the channel was studied.

关键词： quasi-three-dimensional rheological viscosity processing influence

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Rheological behavior’s effect on the work performance of oil film

Zhaomiao LIU, Qiuying JIN, Chengyin ZHANG, Feng SHEN

《机械工程前沿（英文）》 2011年第6卷第2期页码 254-262 doi: 10.1007/s11465-011-0129-y

摘要：

A 3D model of hydrostatic turntable’s oil chamber is established to investigate the lubricants performance with different rheological properties by using FLUENT software and the finite volume method. Newtonian oil and non-Newtonian oil’s performance under varied speeds are compared on the large size hydrostatic turntable system considering the temperature-viscosity relationship and pressure-viscosity relationship. The results show that the property of non-Newtonian fluid viscosity influenced by shear rate largely affects the lubricants performance for most oil added polymer additives. Lubricants cannot simply be regarded as Newtonian fluid. The shear thickening non-Newtonian fluid has a better work property. The results are important to design a large size and high-speed hydrostatic support system, choose lubricant oils, and investigate oil film’s work properties.

关键词： non-Newtonian fluid rotation speed pressure on wall viscosity

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Numerical simulation on flow of ice slurry in horizontal straight tube

Shengchun LIU,Ming SONG,Ling HAO,Pengxiao WANG

《能源前沿（英文）》 2021年第15卷第1期页码 201-207 doi: 10.1007/s11708-017-0451-0

摘要： Numerical simulation on flow of ice slurry in horizontal straight tubes was conducted in this paper to improve its transportation characteristics and application. This paper determined the influence of the diameter and length of tubes, the ice packing factors (IPF) and the flow velocity of ice slurry on pressure loss by using numerical simulation, based on two-phase flow and the granular dynamic theory. Furthermore, it was found that the deviation between the simulation results and experimental data could be reduced from 20% to 5% by adjusting the viscosity which was reflected by velocity. This confirmed the reliability of the simulation model. Thus, two mathematical correlations between viscosity and flow velocity were developed eventually. It could also be concluded that future rheological model of ice slurry should be considered in three sections clarified by the flow velocity, which determined the fundamental difference from single-phase fluid.

关键词： ice slurry horizontal tubes numerical simulation pressure drop viscosity model

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Modeling and analysis of controllable output property of cantilever-beam inertial sensors based on magnetic fluid

Guixiong LIU, Peiqiang ZHANG, Chen XU

《机械工程前沿（英文）》 2009年第4卷第2期页码 129-133 doi: 10.1007/s11465-009-0035-8

摘要： Magnetic fluid is first introduced into the traditional cantilever-beam senor. Based on the property of the cantilever-beam and the novel controllable mag-viscosity of magnetic fluid, the output of cantilever-beam sensors is under control so that the controllable output of the sensors can be realized. The mathematical model of the sensors is established and analyzed. The dynamic control function and the following educational results, which include the two curves of the displacement ratio and phase function with the different damping ratio and frequency ratio, are obtained based on the model. The result shows that it is valid to realize the controllable output of the sensors by controlling the viscosity of the magnetic fluid, and finally the expanded measurement range can be realized.

关键词： sensors magnetic fluid property of mag-viscosity controllable output

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Electrocatalytic reduction of NO to NH in ionic liquids by P-doped TiO nanotubes

《化学科学与工程前沿（英文）》 2023年第17卷第6期页码 726-734 doi: 10.1007/s11705-022-2274-8

摘要： Designing advanced and cost-effective electrocatalytic system for nitric oxide (NO) reduction reaction (NORR) is vital for sustainable NH₃ production and NO removal, yet it is a challenging task. Herein, it is shown that phosphorus (P)-doped titania (TiO₂) nanotubes can be adopted as highly efficient catalyst for NORR. The catalyst demonstrates impressive performance in ionic liquid (IL)-based electrolyte with a remarkable high Faradaic efficiency of 89% and NH₃ yield rate of 425 μg·h⁻¹·mg_cat.⁻¹, being close to the best-reported results. Noteworthy, the obtained performance metrics are significantly larger than those for N₂ reduction reaction. It also shows good durability with negligible activity decay even after 10 cycles. Theoretical simulations reveal that the introduction of P dopants tunes the electronic structure of Ti active sites, thereby enhancing the NO adsorption and facilitating the desorption of *NH₃. Moreover, the utilization of IL further suppresses the competitive hydrogen evolution reaction. This study highlights the advantage of the catalyst−electrolyte engineering strategy for producing NH₃ at a high efficiency and rate.

关键词： nitric oxide reduction reaction electrcatalysis ammonia production phosphorus-doped titania